铝灰的回收处理及资源化利用研究现状

铝灰是铝工业生产过程中产生的有害固体废物,每年的产生量达到上百万吨。铝灰的大量堆积会引起严重的环境与公共安全问题。铝灰中含有较多的金属铝及其氧化物、氮化物,综合回收利用铝灰对减少环境压力、提升铝行业的经济效益具有重要意义。阐述了铝灰的火法和湿法处理工艺,通过比较得出无盐火法工艺和湿法工艺是值得开发的工艺。介绍了铝灰在耐火材料、陶瓷产品、氢气制备以及工程材料等领域的综合利用现状及研究进展。指出在进一步巩固和发展铝灰原有的高附加值资源化利用的同时,应加强对铝灰处理过程中产生的气体的利用。建议根据铝灰的特性进一步开发新的资源化利用方向。     

Transparent niobate glass-ceramics for optical limiting

The construction of nonlinear optical materials featuring asymmetric transmission of light is of great technological importance for various applications, including optical switching and optical power limiting. A significant challenge is the scalable fabrication of material candidates with good photochemical stability, high optical transmittance, and excellent optical limiting performance. Here, we present a nanocrystallization avenue for constructing hybrid optical limiting materials that exhibit ultrafast and robust optical limiting performance. The experimental results show that the controllable relaxation of a niobate glass may lead to the clustering of Nb-O units and contracting of the bandgap. It results in the notable improvement in nonlinear optical properties, including the enhanced saturation irradiance (380 GW/cm²), doubly increased nonlinear coefficient, and decreased limiting threshold (200 GW/cm²). Our results suggest a promising material that exhibits promising applications for protecting eyes and sensitive components from laser-induced damage.     

水资源承载力分析研究

水是人们生存必不可少的资源,是生产与生活的基础,但水资源短缺,时间、空间分布不均,利用率低,已成为制约各地经济可持续发展的重要因素之一。本文所选研究区域——昌宁县正处于经济快速发展时期,水资源承载力将会影响其发展,文章综合文献分析和实际调研数据,运用科学的方法进行水资源的承载力分析,结果表明:昌宁县水资源承载力目前与社会经济的发展相适应,但远期将会有所不足,因而要求协调人与自然的矛盾,促进昌宁县的可持续发展。     

Formation of Chlorotriophenoxy Radicals from Complete Series Reactions of Chlorotriophenols with H and OH Radicals

The chlorothiophenoxy radicals (CTPRs) are key intermediate species in the formation of polychlorinated dibenzothiophenes/thianthrenes (PCDT/TAs). In this work, the formation of CTPRs from the complete series reactions of 19 chlorothiophenol (CTP) congeners with H and OH radicals were investigated theoretically by using the density functional theory (DFT) method. The profiles of the potential energy surface were constructed at the MPWB1K/6-311+G(3df,2p)//MPWB1K/6-31+G(d,p) level. The rate constants were evaluated by the canonical variational transition-state (CVT) theory with the small curvature tunneling (SCT) contribution at 600–1200 K. The present study indicates that the structural parameters, thermal data, and rate constants as well as the formation potential of CTPRs from CTPs are strongly dominated by the chlorine substitution at the ortho-position of CTPs. Comparison with the study of formation of chlorophenoxy radicals (CPRs) from chlorophenols (CPs) clearly shows that the thiophenoxyl-hydrogen abstraction from CTPs by H is more efficient than the phenoxyl-hydrogen abstraction from CPs by H, whereas the thiophenoxyl-hydrogen abstraction from CTPs by OH is less impactful than the phenoxyl-hydrogen abstraction from CPs by OH. Reactions of CTPs with H can occur more readily than that of CTPs with OH, which is opposite to the reactivity comparison of CPs with H and OH.     

Porous sunflower plate-like NiFe2O4/CoNi–S heterostructure as efficient electrocatalyst for overall water splitting

Constructing high-efficient and nonprecious electrocatalysts is of primary importance for improving the efficiency of water splitting. Herein, a novel sunflower plate-like NiFe₂O₄/CoNi–S nanosheet heterostructure was fabricated via facile hydrothermal and electrodeposition methods. The as-fabricated NiFe₂O₄/CoNi–S heterostructure array exhibits remarkable bifunctional catalytic activity and stability toward oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) in alkaline media. It presents a small overpotential of 219 mV and 149 mV for OER and HER, respectively, to produce a current density of 10 mA cm^?2. More significantly, when the obtained electrodes are used as both the cathode and anode in an electrolyzer, a voltage of 1.57 V is gained at 10 mA cm^?2, with superior stability for 72 h. Such outstanding properties are ascribed to: the 3D porous network structure, which exposes more active sites and accelerates mass transfer and gas bubble emission; the high conductivity of CoNi–S, which provides faster charge transport and thus promotes the electrocatalytic reaction of the composites; and the effective interface engineering between NiFe₂O₄ (excellent performance for OER) and CoNi–S (high activity for HER), which leads to a shorter transport pathway and thus expedites electron transfer. This work provides a new strategy for designing efficient and inexpensive electrocatalysts for water splitting.     

底板带压开采工作面并行电透视探测技术应用研究

汾西矿务局水峪矿部分工作面现已面临带压开采问题，受下伏奥陶系灰岩水害影响，工作面安全回采过程中的防治水工作难度增加，尤其是带压开采工作面底板灰岩水的有效探测变得异常紧迫与重要。为了解决底板带压开采工作面富水区的探测问题，水峪矿引入了并行电透视技术，并对相应工作面进行了探测应用。并行电透视技术相对于传统音频电透视技术具有仪器智能化控制发射接收切换、一发射点并行对应多接收点、仪器智能快速高效跑极施工的3项技术优势，可体现应用现场施工高效、实际探测效果可靠的技术特点。经过对并行电透视技术及探测应用效果分析研究，证明该方法技术领先，现场施工高效，实际探测结果可靠，实用性强。     

高强不锈钢绞线网与ECC黏结-滑移关系模型

高强不锈钢绞线网与ECC的黏结是二者协同工作的基础，且黏结 滑移关系模型是其黏结性能的综合反映，故通过对17组51个高强不锈钢绞网增强ECC薄板试件进行单边拉拔试验，研究横向钢绞线间距、纵向钢绞线直径和相对锚固长度等因素对钢绞线网在ECC中黏结性能的影响规律。试验结果表明，横向钢绞线的设置可使黏结破坏由脆性破坏转变为延性破坏；高强不锈钢绞线网与ECC的黏结滑移曲线可分为5个阶段，分别为上升段、微降段、延性强化段、下降段和残余段。基于试验结果，对钢绞线网在ECC中的黏结破坏特征和黏结 滑移机理进行分析，在相关黏结-滑移关系模型的基础上，提出钢绞线网与ECC的黏结 滑移关系模型，并进行模型参数分析。所提模型及模型参数计算公式与试验结果吻合良好，能较好地反映钢绞线网与ECC的界面黏结滑移特征。     

制备金属铪的新进展

金属铪在核能、航天以及军工领域有着得天独厚的优势,国内外对于金属铪的研究正如火如荼的进行。锆铪相伴而生,本文介绍了锆铪的火法和湿法分离,综述了金属热还原法和熔盐电脱氧法制备金属铪通过熔盐电解法、碘化精练法、电子束熔炼法精炼金属铪,就各种方法的优缺点和绿色生产的需求来看,新型熔盐电脱氧法和联合精炼法是值得发展和探究的方向。     

Effects of anion and cation doping on the thermoelectric properties of n-type PbS

The PbCl_xS_1-x and Pb_1-xBi_xS (x? =?0–0.05) bulks were fabricated with a facile method of hydrothermal synthesis and microwave sintering, and the effect of anionic and cationic donors on the thermoelectric performance of PbS was investigated. Although Cl^? and Bi³⁺ both effectively improved the thermoelectric properties of n-type PbS, more excellent thermoelectric performance was obtained from Cl^? doped samples because of higher electrical property and lower thermal conductivity at higher temperature (T? >?600?K). The thermoelectric figure of merit (ZT) reaches 1.04 for PbCl_0.015S_0.985 at 800?K and increases with temperature increasing without sign of saturation, which is probably the highest value ever reported for single-phase polycrystalline n-type PbS. The results also indicate that the hydrothermal synthesis and microwave sintering can realize anion doping as well as cation doping for n-type PbS at low cost, and PbS should be a robust alternative for PbTe thermoelectric materials.